Solution:The molar volume of Sr is (87.6 g mol –1) / (2.60 g cm –3) = 33.7 cm 3 mol –1 Use this value to estimate the radius of the atom of Sr, whose atomic weight is 87.6. The density of metallic strontium is 2.60 g cm –3. Problem Example 8: Radius of a Strontium Atom This is definitely not the case with gases, whose molar volumes must be calculated for a specific temperature and pressure. For solids and liquids, these variables ordinarily have little practical effect, so the values quoted for 1 atm pressure and 25☌ are generally useful over a fairly wide range of conditions. Molar volume depends on the density of a substance and, like density, varies with temperature owing to thermal expansion, and also with the pressure. This is the volume occupied by one mole of a pure substance. Is this answer reasonable? (Always be suspicious of huge-number answers!) Yes, because we would expect to have huge numbers of atoms in any observable quantity of a substance. Solution: Each gram of chlorophyll contains 0.0268 g of Mg, atomic weight 24.3. How many atoms of Mg will there be in 1.00 g of chlorophyll? The plant photosynthetic pigment chlorophyll contains 2.68 percent magnesium by weight. Problem Example 6: Magnesium in Chlorophyll The standard of mass, the kilogram, is not precisely known, and its value appears to be changing.The silicon sphere is an artifact, rather than being something that occurs in nature, and thus may not be perfectly reproducible.(The measurement was made by X-ray scattering.) When combined with the measured mass of this sphere, it yields Avogadro's number. The current value was determined by measuring the distances between the atoms of silicon in an ultra-pure crystal of this element that was shaped into a perfect sphere. Because large numbers of atoms cannot be counted directly, a variety of ingenious indirect measurements have been made involving such things as Brownian motion and X-ray scattering. The value of N A can be known only to the precision that the number of atoms in a measurable weight of a substance can be estimated. Its practical use is limited to counting tiny things like atoms, molecules, formula units, electrons, or photons. It is a huge number, far greater in magnitude than we can visualize. It is a number, just as is dozen, and thus is dimensionless. Things to understand about Avogadro's number N A But if we consider a weight of substance that is the same as its formula (molecular) weight expressed in grams, we only have to know one number: Avogadro's number, 6.022141527 × 10 23, usually designated by N A. The number will of course depend both on the formula of the substance and on the weight of the sample. Once this has been done, we know the number of formula units (to use the most general term for any combination of atoms we wish to define) in any arbitrary weight of the substance. But much as we do when " counting" beans in a jar, we can estimate the number of particles in a sample of an element or compound if we have some idea of the volume occupied by each particle and the volume of the container. Owing to their tiny size, atoms and molecules cannot be counted by direct observation. The mole concept provides this bridge, and is central to all of quantitative chemistry. We also need a bridge between these numbers, which we are unable to measure directly, and the weights of substances, which we do measure and observe. These numbers are HUGE – far too large in magnitude for us to count or even visualize, but they are still numbers, and we need to have a way to deal with them. In the future, it will offer strong scripting abilities to allow for automated demos, submission of calculations to local computational resources, and user-defined customization.Īvogadro 2 is being developed as part of the Open Chemistry project by an open community, and was started at Kitware as an open source community project.The chemical changes we observe always involve discrete numbers of atoms that rearrange themselves into new configurations. etc.Īvogadro is based on top of existing chemistry software, including Open Babel. So Avogadro seeks to allow users to easily provide their own plugins and scripts for rendering, tools, commands. Each community has their own needs and goals for an ideal tool. The main concept behind Avogadro is to enable a strong framework for molecular visualization and editing. It offers flexible rendering and a powerful plugin architecture. Avogadro 0.6.1 on KDE 4 showing ring, stick and VdWĪvogadro is an advanced molecular editor designed for cross-platform use in computational chemistry, molecular modeling, bioinformatics, materials science, and related areas.
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His dialogue is very well written and memorable.He is strict when he needs to be, and kind when he needs to me.He is great friends with Bilbo Baggins and the dwarves, and has great chemistry with them.John Huston does a good job voicing him in the animated movie The Hobbit.His power grows even greater after he is resurrected. He is probably one of few to have ever defeated a Balrog.He is wise, careful, and a good leader. Bilbo Baggins - Hobbit - Name: Bilbo Baggins The hobbit, a resident of the decent, orderly, and decidedly unadventurous region of Hobbiton, Under the Hill.His wisdom has helped many people throughout the years. Ian McKellan portrays him very well in the live-action films. Alex Gandalf Character Analysis Rough draft 3 Gandalf is extremely wise.He has been portayed by several actors over several adaptations, but arguably the most famous is Ian McKellan in Peter Jackson's The Lord of the Rings and The Hobbit film trilogies. Gandalf Mordor locations boog 1 F lacchio Aragon MOVIES Straight frodo fredo. Besides the obvious physical descriptions, pick two or three character traits. He is a wise, powerful wizard who helps defeat a dragon, leads an army against the evil Sauron, and the helps save Middle-earth. character would be connected to the location where they spoke and the. Gandalfs words and actions, then write a paragraph describing Bilbo Baggins. Gollum is so alone that he speaks only to himself, even on the rare occasions when he finds himself with someone else, as he does with Bilbo in Chapter 5. Tolkien's The Hobbit and The Lord of the Rings. Like Smaug, his solitary life is a clue to his wicked nature all other characters in the book, even the evil Goblins and Wargs, are members of communities. Gandalf is one of the main protagonists of the late J.R.R. Richie is oddly considerate of Eddie for someone who continually teases him, which may explain why Eddie inexplicably likes to hang out with him. When Eddie yells at him for getting mud on him, Richie gets up right away. It’s also important to note that, while Richie is giving Eddie a hard time, he only does the type of teasing that he believes Eddie is comfortable with. Richie often teases the other characters and even jokingly flirts with Beverly and Bill, but Eddie is the only one he repeatedly calls “cute.” It is an oddly specific thing to tease Eddie about. This scene includes all the teasing that Richie reserves only for Eddie. This next interaction is a continuation of Richie and Eddie’s first scene together. Eddie doesn’t mention telling Richie this, so we can assume Eddie kept this to himself to spare his crush’s feelings. Eddie admires Richie for dreaming big but has some reasonable doubts, particularly that Richie is bad at ventriloquism because everyone can see his lips moving. It is a personal thing for Richie to share, which suggests that Eddie is a person he feels comfortable being serious with from time to time. It is well known by the other characters that Richie likes Voices and ventriloquism, but as far as we know, Eddie is the only person he has voiced this dream to. Richie isn’t all jokes all the time, however, as shown in this flashback scene where he confesses his life’s ambition to Eddie. This distance between him and Eddie is intentional, due to Richie’s tendency to use humor as a tactic to distract others from his true feelings. Richie is an oddball, who Eddie admits he doesn’t understand.Įddie doesn’t have the same insight into Richie’s emotions as Richie does for his because he can’t properly interpret them. Richie only teases Eddie because he knows that Eddie likes it deep down, an assumption that is later confirmed by adult Eddie. Richie’s line “‘You love it, Eds’” shows that Richie is aware of this and pays close attention to Eddie’s emotions. Richie is known as a jokester and his teasing exasperates Eddie, but he doesn’t feel antagonized by it. This creates a special ritual between the two of them that they both partake in: Richie uses the same language and behavior to joke around with Eddie, and Eddie has the same exasperated response. Richie’s teasing follows a specific criteria: he calls Eddie “Eds,” pinches his cheek, and often calls him “cute,” as shown in later scenes. Richie and Eddie scenes that are both very cute and very gayĮddie and Richie’s first on-page interaction happens when Richie and Stan show up at the Barrens, and Richie immediately begins teasing Eddie like a boy pulling on the pigtails of a girl he likes. Now that I have analyzed each character’s background and behavior, we can explore the queer subtext present in Richie and Eddie’s scenes in the novel. This guest article is written by Rachel Brands (on Twitter Tozier and Eddie Kaspbrak’s relationship has been speculated about since “It” by Stephen King was published in 1986 and was finally legitimized by “It: Chapter 2” in fall of 2019. We don’t have a firm date for Halo Infinite just yet, but the game will launch on PC and Xbox simultaneously, a first for the series. The trailer introduces the story for Season 1 of Halo Infinites multiplayer, which launches. Halo Infinite’s multiplayer will launch with cross-play and cross-progression on both Windows PC and Xbox. 343 Industries revealed a new cinematic trailer for Halo Infinite at Gamescom Opening Night Live. Microsoft and 343 Industries first revealed details on Halo Infinite’s free-to-play multiplayer in July of last year. Halo 2 is the second installment in the Halo franchise and the sequel to 2001s critically acclaimed Halo: Combat Evolved. There’s a particularly fancy clip of one Spartan using the new grappling hook to gain some ground and kill an enemy using a sniper rifle mid-air without aiming - prompting the famous Halo announcer to shout “no scope.” Halo 2 is a 2004 first-person shooter game developed by Bungie and published by Microsoft Game Studios for the Xbox console. I dont think these two additions are enough to staple Halo back on top. We got to see new renderings of vehicles like the Brute Chopper and the rocket Warthog variant. At E3 2021, Microsoft unveiled two new trailers for the game, one showcasing the multiplayer campaign and the other a general story trailer. Halo Infinite will be the same as 5 in terms of being very good in its genre, but the only difference is being free to play multiplayer and coming to PC with hopefully a very good port (unlike MCC). The multiplayer reveal trailer showed off a combination of classic weapons and new ones. While Xbox head Phil Spencer originally suggested that the Halo team might launch the Halo Infinite campaign and multiplayer modes separately, 343 Industries confirmed that the entire package will launch together in 2021. The company confirmed that Halo Infinite will launch this holiday after Microsoft delayed it out of the Xbox Series X launch window last year. The stream description officially calls out the game’s “sandbox”, Academy bots, customization, and what the team is working on ahead of launch.ĭuring its 2021 E3 livestream, Microsoft revealed a new story trailer for Halo Infinite and an initial multiplayer reveal. IGN got a chance to sit down with 343 Industries developers Chris Lee and Paul Crocker to reveal more about the. You can play multiplayer now and you’ll be able to play the campaign. For even more information about Halo Infinite's multiplayer features be sure to. Halo Infinite is available now on Xbox and PC. Announced during Gamescom 2021’s Opening Night Live stream, the Halo Infinite campaign release date is December 8, 2021. The livestream will provide even more details around Halo Infinite’s free-to-play multiplayer. Ultimately, we wont know anything for sure until Microsoft, 343 Industries, and Certain Affinity publicly reveal Project Tatanka to the world. Microsoft and 343 Industries will host a Halo Infinite multiplayer stream on Monday, at 11 a.m. A relaxing rest will give you the energy to go on a vigorous adventure the next day. Sometimes you can fish and enjoy the peace. If you have a fateful encounter with a cat, the cat may want to spend every day with you. By Heidi Nicholas, Follow topics Developer SUNNY SIDE UP has announced an Early Access release date for its charming pixel adventure Little Witch in the Woods, and confirmed that. Their each personality will be as different as appearances. Communicate with cats living in various places. The witch and the cat are inseparable partnerships historically. If you give them a gift that suits their taste, you will be able to get closer to your friends more quickly. Interact with various creatures and fill in the information in the witch's book!įind a hidden place! You can get special items or find shortcuts there.Ĭhat with new friends and find out their tastes. You can find unique areas, and you can meet cute creatures there. Gather and Process materials to create potions! The potions are useful in solving problems.Įxplore a mysterious fantasy world. Trong nhng nm qua, ta game nông tri ni ting Stardew Valley ã truyn cm hng cho nhiu sn phm khác, nhng ít có phép thut nào c a vào trong trò chi. If you can be their best friend, you maybe hear their secret. Trò chi mi Little Witch in the Woods kt hp cuc sng lành mnh ca mt th trn nh Stardew Valley vi phép thut ca Harry Potter. Make friends with the charming characters in village, and listen to the inner story they bear. Practice the teachings you learned at the Witch School, help people and make the world a better place. Become Ellie the Apprentice Witch and experience her daily life!īecome the main character, Ellie, and proceed with the story so that you can complete your apprenticeship successfully. If you complete your apprenticeship successfully, you can become a formal witch. The apprentice witches must go to the one of the 'Witch's Houses' and help the nearby village and villagers. They built 'Witch House' in various areas and have been sending their apprentice witches there. In the 'LUCEREIN ORTU', witches live together. "Play a little witch's daily life as apprentice" Purchase only if you are comfortable with the current state of the unfinished game. It may or may not change over time or release as a final product. When confronted with the need to free up storage on your Mac we’re guessing that your first port of call was About This Mac, where there is a handy tool to help you manage your storage – and it’s here that we’re assuming you saw a gigantic Other category (as we explained above, you will only see Other in older versions of macOS, so if you don’t see Other here, you will be better off reading this article). We also discuss How to delete Other on an iPhone separately. While Apple has moved on from Big Sur and the older operating systems, a lot of people are still running them and therefore looking for ways to delete Other storage, so in this article, we will address how to get rid of Other storage, and we also the things you can delete if you feel something is taking up too much space. In macOS Ventura and Sonoma you’ll also see System Data and macOS.Įssentially the contents of the Other folder has now been clumped together with the System and System Data folders you might find on machines with newer operating systems. In Monterey rather than Other you would find a listing for macOS and System Data in your storage outline. However, macOS Monterey brought a big change to the way that macOS displays the different kinds of storage. Prior to macOS Monterey if you clicked on the Apple logo > About This Mac > Storage you’d have seen a bar chart labeled with various categories of data – one of these was Other. Get a Free Edition 2023 Other and System Dataīefore we begin, you may not even see Other as a category of storage at all. If you aren’t sure how to see how much disk space your Mac has read: How to check how much storage you have on your Mac. We also run through various ways to free up space on your Mac in a separate article. Plus we’ll explain how you can reduce the amount of space Other is taking up on your Mac and what you can delete from Other storage on Mac. If you are wondering what is Other in Mac storage and want to know if you can delete Other storage – and if you should, we will answer your questions. In that case, you should take a look at our explanation of how to delete System Data on a Mac. NOTE: You won’t see storage listed as Other in macOS Monterey and later. After all, Other is just ‘stuff’ isn’t it? It’s a name that screams “Delete me!” It can’t be anything you actually need… Or can it? So, if when investigating what is taking up so much of your valuable storage space you find a mysterious section labeled Other, you are likely to think that sounds like a great way to regain tens of gigabytes of space on your drive. Amateurs who are new to digital editing and image management tools will find everything they need to learn about digital photography from ACDSee's handy array of video tutorials. The multimedia package is available with a thirty-day free trial but thereafter, users need to pay for a lifetime license. Furthermore, the package allows users to gain access to over 100 pre-loaded borders and textures. The standard edition will connect and upload to social media sites while you continue operating on your workflow which is another great time-saving measure. So, if you upgrade down the line, there is nothing new to learn in terms of operation, helping you to remain productive. Moreover, the functions users have access to, such as a number of useful keyboard shortcuts, are the same with the higher editions. Nevertheless, there are some handy tools to try out, such as the noise reduction module and the ability to control white and color balances as well as helpful tint and saturation functions.įor users who want some level of image editing and a powerful organizational tool, the standard edition of the package is likely to be enough. For example, you don't get RAW editing with the standard edition. The Ultimate and Professional versions of ACDSee Photo Studio allow for a lot more functionality on the image manipulation front. As such, the Standard edition of ACDSee Photo Studio Home is very much part of a wider family of programs each focused on a specific area of image creation. Software, already offer a complete package of photography software, from their Photo Editor to their Video Converter and Video Studio software. The makers, ACD Systems International Inc. What's more, you can connect to your library via a handheld device using a mobile app, great for when you want to show particular images off in a social way. Helpfully, ACDSee Photo Studio Home provides what the designers call a digital asset management module which makes finding, sorting and sharing images a breeze. Organizing your images so that you can find what you need just when you want it is something all image makers struggle with, especially if they don't have the right digital tools to help them. It also makes all sort of intelligent adjustments to images possible without long-winded processes. ACDSee Photo Studio Home is designed for amateur photographers who want to organize their images in a meaningful way so they can be found, shared and edited with the minimum of fuss. Intuitive graphical comparison result viewįile date - the time part can be disabledĬompatibility: OS X 10. DirEqual displays compared files and directories side by side to help you visualize their size and changes from the dashboard. You can drag your files and directory easily using this app and even create snapshots for your directories for archiving and future comparison. This page is powered by a knowledgeable community that helps you make an informed decision. DirEqual offers control keywords, something that Beyond Compare doesn’t have. 'Supports editing files directly' is the primary reason people pick Meld over the competition. There are more than 25 alternatives to DirEqual for a variety of platforms, including Windows, Linux, Mac, Web-based and BSD apps. Remembers compared folders for quick reload Meld, KDiff3, and Helix Visual Merge Tool (P4Merge) are probably your best bets out of the 16 options considered. DirEqual is described as Folder Compare Tool that makes it extremely easy to compare local files and folders on your Mac and is a Diff Tool in the file management category. Then click “Execute” to synchronise the two folders.Ĭompare items based on a filename template The action is represented with red or blue arrow. To copy or delete files or folders, click an individual item to choose the appropriate action. Differences between the directories are indicated with colour and easy to identify icons. Download now DirEqual is a tool that makes it incredibly easy to compare local files and folders on your Mac. If you would like to compile the project yourself and. DirEqual is a Folder Compare Tool that makes it extremely easy to compare local files and folders on your Mac.ĭirEqual displays compared directories side by side as expandable trees, and the size and date are indicated for each item. Hardwareeing open source, you are free to use the ESPixelStick firmware on the device of your choice. |
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